Preparation, characterization and properties of dipolar 1, 2-N, N-dimethylaminomethylferrocenylsilanes

C Beyer, U Böhme, C Pietzsch, G Roewer

文献索引：Beyer, Christian; Boehme, Uwe; Pietzsch, Claus; Roewer, Gerhard Journal of Organometallic Chemistry, 2002 , vol. 654, # 1-2 p. 187 - 201

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被引用次数: 24

摘要

A series of substituted 1, 2-N, N-dimethylaminomethylferrocenyl compounds were synthesized and characterized by 1H-NMR, 13C-NMR, 29Si-NMR, ES–MS, IR, UV–vis and 57Fe-Mössbauer spectroscopy. The new (R, S)-2-(N, N-dimethylaminomethyl) ferrocenyl- (aryl) silanes (R, S)-FcNSiMen (C6H4X) m (n= 2–0, m= 1, X= pF (5); m= 2, X= pF (6); m= 3, X= pF (7) and m= 1, X= p-Br (14) were formed by the reaction of 2- ...