Application of the conformational transmission effect for the assignment of diastereotopic proton resonances

MHP van Genderen, HM Buck

文献索引：Genderen, Marcel H. P. van; Buck, Henk M. Magnetic Resonance in Chemistry, 1987 , vol. 25, p. 872 - 878

全文：HTML全文

被引用次数: 1

摘要

Abstract A new method is presented for the assignment of the NMR resonances of the diastereotopic protons in tetrahydrofur-furyl and pyrrolidinylmethyl groups, based on the conformational transmission effect This effect describes the conformational changes produced by an increase of coordination from four to five of a phosphorus, silicon or germanium atom attached to the tetrahydrofurfuryl or pyrrolidinylmethyl moieties. The 1 H ...