Organosilicon compounds. XCII. The effect of structure of some organosilicon thiols on the rate of their addition to phenyl isocyanate

J Hetflejš, L Svoboda, M Jakoubkova…

文献索引：Hetflejs,J. et al. Collection of Czechoslovak Chemical Communications, 1973 , vol. 38, p. 717 - 726

全文：HTML全文

被引用次数: 6

摘要

A kinetic study was made of the addition of alkylsilylsubstituted thiols (CH3hSi (CH2) nSH (n= 1-4) and siloxysilyl-substituted thiols [(CH3hSiOh-n (CH3) nSiCH2SH (n= 1-3) to phenyl isocyanate catalysed with triethylamine. It was found that the reaction is first order in the reactants and the catalyst. In harmony with the proposed mechanism, the reactivity of the trimethylsilyl-substituted thiols decreased with decreasing influence of the+ 1 effect of ...