Aluminiumalkyle mit heteroatomen: VII. Über reaktionen von nitrilen mit tris (3-trimethylsilyl-propyl) aluminium

G Sonnek, KG Baumgarten, H Reinheckel…

文献索引：Sonnek,G. et al. Journal of Organometallic Chemistry, 1978 , vol. 150, p. 21 - 26

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被引用次数: 3

摘要

Abstract Aliphatic nitriles react with tris (3-trimethylsilylpropyl) aluminium forming 1- trimethylsilyl-alkan-4-ones upon hydrolysis while benzonitrile is reduced to benzaldehyde even at room temperature. The properties of the complex and the course of the reaction have been investigated spectroscopically.