The Journal of Physical Chemistry

Rate constants (296-1700 K) for the reactions ethynyl radical+ acetylene. fwdarw. C4H2+ H and C2D+ C2D2. fwdarw. C4D2+ D

KS Shin, JV Michael

文献索引：Shin, Kuan S.; Michael, J. V. Journal of Physical Chemistry, 1991 , vol. 95, # 15 p. 5864 - 5869

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被引用次数: 54

摘要

Rate constants for the reactions C2H+ C2H2-. C4H2+ H and C2D+ C2D2-+ C4D2+ D have been measured over the temperature range 296-1475 and 1226-1700 K, respectively. For the high-temperature experiments, the method was the laser photolysis-shcck tube technique (LP-ST); however, for the room-temperature experiments, the laser photolysis- resonance absorption (LP-RA) technique was used. These techniques utilize the atomic ...