Hydrocarboxylation of terminal alkenes in supercritical carbon dioxide

…, A Orejón, N Ruiz, AM Masdeu??Bultó…

文献索引：Estorach, Clara Tortosa; Orejon, Arantxa; Ruiz, Nuria; Masdeu-Bulto, Anna M.; Laurenczy, Gabor European Journal of Inorganic Chemistry, 2008 , # 22 p. 3524 - 3531

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被引用次数: 13

摘要

Abstract The catalytic hydrocarboxylation of linear alkenes to carboxylic acids using supercritical carbon dioxide as a solvent was studied. High selectivities in acids have been obtained. The best results were achieved when adding a perfluorinated surfactant to the reaction mixture (93% conversions and ca. 80% selectivity). Comparative multinuclear high- pressure NMR spectroscopic studies in [D 8] THF and in supercritical CO 2 show the ...