Substituent and solvent effects on intramolecular charge transfer of 5-arylidene-2, 4-thiazolidinediones

…, N Trišović, M Milčić, G Ušćumlić, A Marinković

文献索引：Rancic, Milica; Trisovic, Nemanja; Milcic, Milos; Uscumlic, Gordana; Marinkovic, Aleksandar Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2012 , vol. 86, p. 500 - 507

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被引用次数: 12

摘要

The absorption spectra of twelve 5-arylidene-2, 4-thiazolidinediones were recorded in twenty one solvents in the range from 300 to 600nm. The effect of specific and non-specific solvent–solute interactions on the absorption maxima shifts were evaluated by using the Catalán solvent parameter set. Furthermore, the experimental findings were interpreted with the aid of ab initio MP2 and time-dependent density functional (TD-DFT) methods. It was ...