Synthesis and properties of 1-and 2-(dichloromethyl) heptamethyltrisilane and related compounds

H Sakurai, H Yamamori, M Kumada

文献索引：Sakurai,H. et al. Journal of Organic Chemistry, 1968 , vol. 33, # 4 p. 1527 - 1530

全文：HTML全文

被引用次数: 7

摘要

The first carbon-functional organotrisilanes, 1-and 2-(dichloromethyl) heptamethyltrisilane, have been prepared from the corresponding chloroheptamethyltrisilanes with a- dichloromethyllithium. 1-(Chloromethy1)-heptamethyltrisilane as well as (chloromethy1) pentamethyldisilane were also prepared by in situ coupling of bromochloromethane with the corresponding chlorosilanes. Aluminum chloride catalyzed reactions of 1-and 2-( ...