Synthesis of the honey-bee attractant 13-hydroxy-2-oxotridecane

…, OV Botsman, OI Izibairov, AG Mannapov…

文献索引：Ishmuratov; Yakovleva; Kharisov; Botsman; Izibairov; Mannapov; Tolstikov Chemistry of Natural Compounds, 2001 , vol. 37, # 2 p. 190 - 192

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被引用次数: 4

摘要

Abstract 13-Hydroxy-2-oxotridecane, which is isolated from extract of Evodia hupehensis Dode honey-bee eggs and actively attracts honey bees, is synthesized via ozonolysis of 1- methylcyclododecene and tetradec-13-en-2-one, the product from monoalkylation of the acetoacetic ester with 1-bromo-10-undecene followed bydecarbethoxylation, with further reduction of the intermediate peroxides using NaBH (OAc) 3