Heteroatom Chemistry

2, 4, 6??Tri??tert??butylphenyl and 2, 4??di??tert??butyl??6??methylphenyl groups: Look similar, react differently

AS Ionkin, WJ Marshall

文献索引：Ionkin, Alex S.; Marshall, William J. Heteroatom Chemistry, 2002 , vol. 13, # 7 p. 662 - 666

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被引用次数: 26

摘要

Abstract The crystal structures of molecules with two phosphaalkene groups have been determined. Differences in the stabilization of the P [DOUBLE BOND] C π-bond by the 2, 4, 6- tri-tert-butylphenyl and 2, 4-di-tert-butyl-6-methylphenyl groups were observed. It has been found that lithium supermesityl (trimethylsilyl) phosphide could be a very efficient base to remove a proton from acetonitrile.© 2002 Wiley Periodicals, Inc. Heteroatom Chem 13: ...