Hydrogen-bonding interactions involving metal-bound dioxygen

RS Drago, JP Cannady, KA Leslie

文献索引：Drago, Russell S.; Cannady, J. Patrick; Leslie, Kenneth A. Journal of the American Chemical Society, 1980 , vol. 102, # 19 p. 6014 - 6019

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被引用次数: 45

摘要

Abstract: In this article the equilibrium constant and enthalpy for formation of the dioxygen adduct of the bis (sa1icyliden-iminato-3-propyl) methylaminocobalt (II) complex (CoSMDPT) are reported in methylene chloride solution (-9.8 kcal mol-'). When small amounts of 2, 2, 2- trifluoroethanoI (TFE) are added, extra stabilization of the dioxygen adduct is found. The measured enthalpy for adduct formation increases to-1 1.8 kcal mol-'. Infrared frequency ...