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Polymer

Synthesis and gas permeability of ester substituted poly (p-phenylene) s

T Sakaguchi, S Tominaga, T Hashimoto

文献索引:Sakaguchi, Toshikazu; Tominaga, Shinichi; Hashimoto, Tamotsu Polymer, 2011 , vol. 52, # 10 p. 2163 - 2169

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被引用次数: 11

摘要

Abstract Polymerizations of various ester substituted 2, 5-dichlorobenzoates [substituent: linear alkyl groups (1a–f), branched alkyl groups (1g–l), cyclohexyl groups (1m–o), phenyl groups (1p–r), and oxyethylene units (1s–v)] were investigated with Ni-catalyzed/Zn- mediated system in 1-methyl-2-pyrrolidone (NMP) at 80 C. Most of monomers bearing linear and branched alkyl groups successfully polymerized to give relatively high-molecular- ...