Synthesis and characterization of bulky aryl derivatives of the heavier Main Group 3 elements

…, HVR Dias, K Ruhlandt-Senge, KM Waggoner…

文献索引：Petrie, Mark A.; Power, P. P.; Dias, H. V. Rasika; Ruhlandt-Senge, Karin; Waggoner, Krista M.; Wehmschulte, Rudolf J. Organometallics, 1993 , vol. 12, p. 1086 - 1093

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被引用次数: 87

摘要

The synthesis and structural characterization of several bulky aryl derivatives of aluminum, gallium, and indium are described. With the exception of the previously synthesized species Al (Mes) Clz. THF (1) and [Ga (Mes) zClI 2 (6)(Mes= 2, 4, 6-Me&Hz) the compounds are derivatives of the very crowding 2, 4, 6-i-Pr&&-(Trip) or 2, 4, 6-t-BuC~ H~-(Mea*) substituents, as indicated by the formulas Al (Trip) Brz (EtnO)(21,[Al (Trip)~ Brl 2 (3), Ga ( ...