Journal of the American Chemical Society

Molecular asymmetry. VII. Trans-6, 7, 10, 11-Tetrahydro-5H-benzocyclononene

AC Cope, MW Fordice

文献索引：Cope,A.C.; Fordice,M.W. Journal of the American Chemical Society, 1967 , vol. 89, p. 6187 - 6191

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被引用次数: 13

摘要

Abstract: The title compound 1 was prepared and converted into (+)-trans-dichloro-(trans-6, 7, lO, ll-tetrahydro-5H-benzocyclononene)((R)-c~-methylbenzylamine) platinum (II)(8). After fractional crystallization the platinum complex had [a]% f37. 4". Decomposition of the complex at-60" afforded optically inactive trans-olefin 1 sug-gesting that the trans-olefinic linkage in 1 is rotating very rapidly causing spontaneous racemization of olefin 1. The ...