Synthesis of brominated 2-(tert-butyl-NNO-azoxy) anilmes
…, SL Ioffe, YA Strelenko, VA Tartakovsky
文献索引：Churakov, A. M.; Smirnov, O. Yu.; Ioffe, S. L.; Strelenko, Yu. A.; Tartakovsky, V. A. Russian Chemical Bulletin, 1994 , vol. 43, # 9 p. 1532 - 1535 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1994 , # 9 p. 1620 - 1623
Abstract 2-(tert-Butyl-NNO-azoxy) aniline was prepared by selective reduction of 2-(tert-butyl- NNO-azoxy) nitrobenzene. Its bromination yielded the corresponding para-bromo-and ortho, para-dibromoanilines (3a, b). meta-Bromoanilines (6a, b) were synthesized by selective replacement of the ortho-bromine atoms in ortho, para-bromo (tert-butylazoxy) benzenes (5a, b) by ammonia in toluene under pressure.
