Synthesis and Spin Trapping Stereochemistry of the Chiral Spin Trap, 5, 5??Dimethyl??3??phenylpyrroline??1??oxide
…, P Schuler, HB Stegmann, J Lee Poyer…
文献索引：Matasyoh, Josphat C.; Schuler, Paul; Stegmann, Hartmut B.; Poyer, J. Lee; West, Melinda; Janzen, Edward G. Magnetic Resonance in Chemistry, 1996 , vol. 34, # 5 p. 351 - 359
Abstract A chiral spin trap, 5, 5-dimethyl-3-phenylpyrroline-1-oxide (5), and several hydroxylamines were synthesized. The structures and conformations of these compounds were investigated mainly by 1 H NMR spectroscopy. This spin trap was used to trap carbon- and oxygen-centered radicals. The corresponding hydrogen spin adduct was prepared by oxidizing the hydroxylamine to the nitroxide radical. By the combination of 1 H NMR and ...
