Oxidative Entry into the Illicium Sesquiterpenes: Enantiospecific Synthesis of (+)-Pseudoanisatin

K Hung, M Condakes, T Morikawa…

文献索引：Miyake, Hideyoshi; Nishimura, Akinori; Yago, Misato; Sasaki, Mitsuru Chemistry Letters, 2007 , vol. 36, # 2 p. 332 - 333

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摘要

... Herein we document the realization of this blueprint resulting in the first chemical synthesis of pseudoanisatin ... keto-acid 12 to 150 °C in the presence of anhydrous CuBr 2 (3.0 equiv ... reach of the pendant carboxylic acid present, substrate 16 would test the limits of this chemistry. ...