Metal-assisted reactions. Part 25. Heterogeneous and homogeneous catalytic transfer hydrogenolysis of allyloxytetrazoles to yield alkenes or alkanes
M Lurdes S áCristiano, AW Robert
文献索引:Cristiano, M. Lurdes S.; Johnstone, Robert A. W.; Price, Peter J. Journal of the Chemical Society - Perkin Transactions 1, 1996 , # 12 p. 1453 - 1459
Transfer hydrogenolysis of 5-allyloxy-l-phenyltetrazoles using either a heterogeneous or a homogeneous palladium catalyst and a hydrogen donor leads to cleavage of the allyloxy C– O bond to yield an alkane or an alkene and 1-phenyltetrazolone, depending on the catalyst used.