Oxidizing Action of Hydroperoxides. Oxidation of Alkyl Aryl Ketones by Hydroperoxides

K Maruyama, H Iwamoto, O Soga…

文献索引：Maruyama, Kazuhiro; Iwamoto, Hidetoshi; Soga, Osamu; Takuwa, Akio Bulletin of the Chemical Society of Japan, 1982 , vol. 55, # 7 p. 2161 - 2164

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被引用次数: 6

摘要

The oxidation of alkyl aryl ketones by t-butyl hydroperoxide under basic conditions gave products which resulted from the fission of the carbon-carbon bond between carbonyl carbon and alkyl carbon. The reaction was investigated using chiral alkyl aryl ketones. On the basis of the results, a probable reaction mechanism is proposed.