Journal of Organometallic Chemistry

Hydroboration of terpenes I. The selective hydroboration of myrcene with disiamylborane

HC Brown, KP Singh, BJ Garner

文献索引：Brown,H.C. et al. Journal of Organometallic Chemistry, 1963 , vol. 1, p. 2 - 7

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被引用次数: 10

摘要

Abstract The reaction of disiamylborane with myrcene (7-methyl-3-methylene-1, 6- octadiene) occurs selectively to place the boron atom at the 1-position. Oxidation of the resulting organoborane with alkaline hydrogen peroxide yields myrcenol (7-methyl-3- methylene-6-octen-1-ol) identified by infrared and nuclear magnetic resonance spectra. Further hydroboration of myrcenol with disiamylborane, or dihydroboration of myrcene ...