Liquid??phase oxidation of 1??isopropyl??and 1??ethyl??4??methoxybenzenes with oxygen to hydroperoxides

J Zawadiak, Z Stec, B Jakubowski…

文献索引：Zawadiak, Jan; Stec, Zbigniew; Jakubowski, Bartlomiej; Orlinska, Beata International Journal of Chemical Kinetics, 2003 , vol. 35, # 3 p. 89 - 94

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被引用次数: 5

摘要

Abstract A study was carried out on the kinetics of free-radical chain oxidation of 1-isopropyl- 4-methoxybenzene (1a) and 1-ethyl-4-methoxybenzene (1b) with oxygen in the liquid phase to yield 1-methyl-1-(4-methoxyphenyl) ethyl hydroperoxide (2a) and 1-(4-methoxyphenyl) ethyl hydroperoxide (2b). The oxidizability of 1a and 1b was studied over the temperature range 50–100 C. Long-term oxidations of 1a and 1b to the corresponding hydroperoxides ...