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The Journal of Organic Chemistry

Reaction of sulfonimidamide anions with electrophiles

K Okuma, T Koike, H Ohta

文献索引:Okuma, Kentaro; Koike, Tetsufumi; Ohta, Hiroshi Journal of Organic Chemistry, 1988 , vol. 53, # 18 p. 4190 - 4193

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被引用次数: 11

摘要

The reaction of alkylsulfonimidamides with bases gave corresponding carbanions, which were allowed to react with carbonyl compounds to give (2-hydroxyalky1) sulfonimidamides in good yields. When benzoic anhydride or chlorotrimethylsilane was treated with these anions, corresponding phenacylsulfonimidamides or (tri-methylsily1) methylsulfonimidamides were obtained. On the other hand, the reaction of methyl Np- ...