Mild and regiospecific reduction of masked 1, 3-dicarbonyl derivatives to monocarbonyl compounds and primary and secondary amines

J Barluenga, E Aguilar, B Olano…

文献索引：Barluenga, Jose; Aguilar, Enrique; Olano, Bernardo; Fustero, Santos Journal of Organic Chemistry, 1988 , vol. 53, # 8 p. 1741 - 1744

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被引用次数: 10

摘要

The regiospecific reduction of masked 1, 3-dicarbonyl compounds to the corresponding saturated monocarbonyl 3 or iminic 4 compounds via 3-amino-2-alkenimines 1 is described. The formation of 3 or 4 can be explained in terms of a double reduction process from 1. A simple method for the synthesis of primary and secondary amines 6 is also described.