Palladium-catalysed carbonyl allylation by isoprene via regioselective 1, 4-addition of tin hydride formed in situ

Y Masuyama, M Tsunoda, Y Kurusu

文献索引：Masuyama, Yoshiro; Tsunoda, Megumi; Kurusu, Yasuhiko Journal of the Chemical Society, Chemical Communications, 1994 , # 12 p. 1451 - 1452

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被引用次数: 6

摘要

Isoprene reacts with aldehydes in the presence of a catalytic amount of P ~ ( OAC ) ~ ~ PP ~ ~ ... Allylic alcohols and esters can be applied to palladium- catalysed carbonyl allylation with SnC12, in which the forma- tion of a n-allylpalladium complex followed by that of an allylic tin compound are the key steps.' Any substrate, transformed into a n-allylpalladium complex, could be utilized for palladium-catalysed carbonyl allylation with SnC12. Here we report the ...