Studies in the cycloproparene series: 1 chemistry of the 1-trimethylsilyl-1 H-cyclopropa [b] naphthalenyl anion

B Halton, CS Jones

文献索引：Halton, Brian; Jones, Carissa S. Journal of the Chemical Society. Perkin Transactions 2, 1998 , # 11 p. 2505 - 2508

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摘要

Desilylation of 1, 1-bis (trimethylsilyl)-1-cyclopropa [] naphthalene 10 with-butoxide or hydroxide ion gives anion 9 as a highly reactive species. Formed with-butoxide 9 can be intercepted by iodomethane to give the 1-methyl-1-trimethylsilyl derivative 13. With hydroxide ion and water catalytic didesilylation regene