A practical, efficient method for preparation of four possible stereoisomers of secondary allylic alcohols using kinetic resolution of (E)-1-trimethylsilylalk-1-en-3-ol by …
Y Kitano, T Matsumoto, F Sato
文献索引：Kitano, Yasunori; Matsumoto, Takashi; Sato, Fumie Journal of the Chemical Society, Chemical Communications, 1986 , # 17 p. 1323 - 1325
Kinetic resolution of (E)-1-trimethylsilylalk-1-en-3-ol by the Sharpless process, which proceeds with very large rate differences for the two isomers, combined with the reactivity of epoxysilyl compounds affords a practical, efficient method for preparation of four possible stereoisomers of secondary allylic alcohols.
