Tetrahedron

Asymmetric synthesis of bicyclopropane derivatives

AGM Barrett, WW Doubleday, GJ Tustin

文献索引：Barrett, Anthony G. M.; Doubleday, Wendel W.; Tustin, Gary J. Tetrahedron, 1996 , vol. 52, # 48 p. 15325 - 15338

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被引用次数: 19

摘要

Both syn-and anti-bicyclopropane derivatives have been prepared with good relative and absolute stereocontrol using reagent controlled asymmetric cyclopropanation reactions. Double Simmons-Smith cyclopropanation of 2, 4-dien-1-ols stereoselectively gave the corresponding anti-bicyclopropane derivatives.