Comparative solvolytic reactivity of bay-region diol epoxides derived from dibenz [a, j] anthracene and dibenzacridines

…, S Kumar, H Yagi, HJC Yeh, GM Holder…

文献索引：Sayer; Lehr; Kumar; Yagi; Yeh; Holder; Duke; Silverton; Gibson; Jerina Journal of the American Chemical Society, 1990 , vol. 112, # 3 p. 1177 - 1185

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被引用次数: 15

摘要

Abstract: Rates and products have been measured in 1: 9 dioxane-water, ionic strength 0.1 M, at 25 OC for the solvolyses of the two diastereomeric bay-region 3, 4-diol 1, 2-epoxides derived from trans-3, 4-dihydroxy-3, 4-dihydrodibenz [c, h] acridine (diol epoxide-1, in which the epoxide and the benzylic hydroxyl groups are cis to each other, and diol epoxide-2, in which these groups are trans). Comparative study of these diol epoxides and their ...