Journal of the American Chemical Society

The Spectral Properties of Alkoxymethyl Cations1

BG Ramsey, RW Taft

文献索引：Ramsey,B.G.; Taft,R.W. Journal of the American Chemical Society, 1966 , vol. 88, # 13 p. 3058 - 3063

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被引用次数: 58

摘要

Abstract: The results of the first detailed nmr, infrared, and ultraviolet spectroscopic investigations of alkoxymethyl cations (alkoxycarbonium ions) are reported. These ions were studied as Meerwein fluoroborate salts or as generated in acid solutions from corresponding ortho esters or ketals. All of the results are consistent with neaicoplanar structures for (CH30) 3C+(C3h point group indicated),(CH30) 2 CCH 3~, and (CH30) 2CH+, which may be ...