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Ruthenium??Catalyzed Propargylic Reduction of Propargylic Alcohols with Silanes

Y Nishibayashi, A Shinoda, Y Miyake…

文献索引:Nishibayashi, Yoshiaki; Shinoda, Akira; Miyake, Yoshihiro; Matsuzawa, Hiroshi; Sato, Mitsunobu Angewandte Chemie - International Edition, 2006 , vol. 45, # 29 p. 4835 - 4839

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被引用次数: 75

摘要

A number of transition-metal complexes are known to promote the hydrosilylation of alkynes with silanes to give the corresponding vinyl silanes, which are versatile building blocks in organic synthesis.[1] The development of highly stereo-and regioselective hydrosilylation reactions of alkynes with silanes is an important subject in organic synthesis.[1] The selectivity in transition-metal-catalyzed hydrosilylation depends on the nature of catalysts, ...