Journal of the American Chemical Society

Addition of peroxides to conjugated olefins catalyzed by copper salts

JK Kochi

文献索引：Kochi,J.K. Journal of the American Chemical Society, 1962 , vol. 84, p. 2785 - 2793

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被引用次数: 22

摘要

&Butyl peracetate and perbenzoate react with conjugated olefins under catalysis by copper salts to form adducts containing one or more olefin units. From butadiene, t-butoxybutenyl derivatives are formed which are the same as those derived from t-butyl hypochlorite or t- butyl hydroperoxide and ferrous sulfate. It is demonstrated that these t-butyl peresters and copper salts form t-butoxy radicals as intermediates, which add to butadiene to produce t- ...