Catalysis of α-Fe and Fe 1− x S toward the Hydrogenolysis of trans-Stilbene in Hydroaromatic Hydrocarbon Solvents

S Futamura, K Fujimoto, Y Kamiya

文献索引：Futamura, Shigeru; Fujimoto, Ken-ichiro; Kamiya, Yoshio Bulletin of the Chemical Society of Japan, 1990 , vol. 63, p. 2564 - 2568

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被引用次数: 2

摘要

The Fe-catalyzed hydrogenolysis of trans-stilbene was carried out in aromatic hydrocarbon solvents at 380° C. α-Fe and pyrrhotite catalyze bimolecular hydrogen transfer from hydroaromatic hydrocarbons to trans-stilbene and hydroaromatic hydrocarbon-mediated hydrogenolysis of trans-stilbene by molecular hydrogen at 380° C. This catalyzed hydrogen transfer proceeds by radical mechanism. The product distribution is affected by the ...