Journal of the American Chemical Society

Mechanism of aqueous decomposition of trichloroethylene oxide

H Cai, FP Guengerich

文献索引：Cai, Hongliang; Guengerich, F. Peter Journal of the American Chemical Society, 1999 , vol. 121, # 50 p. 11656 - 11663

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被引用次数: 40

摘要

The aqueous decomposition of trichloroethylene (TCE) oxide is shown to involve both pH- independent and hydronium ion-dependent regions. CC bond scission is a major reaction at all pH values. Disappearance of TCE oxide is the rate-determining step for the formation of CO under the conditions studied. The product distribution of CO and three carboxylic acids (HCO2H, Cl2CHCO2H, and glyoxylic acid) did not change considerably over the pH ...