Tetrahedron

Preparation and structure of some tricyclo [3.2. 1.02, 4] octane derivatives

SC Clarke, KJ Frayne, BL Johnson

文献索引：Clarke,S.C. et al. Tetrahedron, 1969 , vol. 25, p. 1265 - 1280

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被引用次数: 15

摘要

The Diels-Alder reaction of 1, 2, 3, 4-tetrachloro-5, 5-< limethoxycyclopenta-1, 3-diene with cyclopropene has been utilized to furnish some endo-tricyclo [3.2. 1.02, 4] octane derivatives. Several exo-tricyclo [3.2. 1.2, 4] octane derivatives were synthesized from known precursors using standard reactions. The stereochemistry of the tetracyclic alcohol, resulting (ultimately) from the reaction of 7-norbornadienyl acetate with diazomethane, is discussed ...