Isoreticular chiral metal− organic frameworks for asymmetric alkene epoxidation: tuning catalytic activity by controlling framework catenation and varying open channel …

…, C Wang, JM Falkowski, L Ma, W Lin

文献索引：Xie, Zhigang; Ma, Liqing; DeKrafft, Kathryn E.; Jin, Athena; Lin, Wenbin Journal of the American Chemical Society, 2010 , vol. 132, # 3 p. 922 - 923

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被引用次数: 409

摘要

A family of isoreticular chiral metal− organic frameworks (CMOFs) of the primitive cubic network topology was constructed from [Zn4 (μ4-O)(O2CR) 6] secondary building units and systematically elongated dicarboxylate struts that are derived from chiral Mn-Salen catalytic subunits. CMOFs 1− 5 were synthesized by directly incorporating three different chiral Mn- Salen struts into the frameworks under solvothermal conditions, and they were ...