Chemische Berichte

Water??soluble tetraoxa [n. 1. n. 1] paracyclophanes: Synthesis and host??guest interactions in aqueous solution

F Diederich, K Dick, D Griebel

文献索引：Diederich, Francois; Dick, Klaus; Griebel, Dieter Chemische Berichte, 1985 , vol. 118, # 9 p. 3588 - 3619

被引用次数: 43

摘要

Abstract The synthesis of water-soluble tetraoxa [n. 1. n. 1] paracyclophanes 1c–8c and open-chained model compounds 14c and 15c is described. 1c–8c possess differently sized cavities of pronounced hydrophobic character as binding site for apolar guests in aqueous solution. In 1c–8c, spiropiperidinium rings locate the water-solubility providing quaternary ammonium nitrogens remote from the cavity. The synthesis of water-insoluble tetraoxa [n. ...