Cyclohexylene-bridged porphyrin quinones with variable acceptor strength as biomimetic models for photosynthesis: Evidence for twist-boat conformation

…, MO Senge, B Kirste, H Kurreck

文献索引：Dieks, Henrik; Senge, Mathias O.; Kirste, Burkhard; Kurreck, Harry Journal of Organic Chemistry, 1997 , vol. 62, # 25 p. 8666 - 8680

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被引用次数: 20

摘要

Rigidly and covalently linked porphyrin quinones are well-suited as biomimetic model compounds for studying the photoinduced electron transfer (PET) reaction occurring in primary processes of photosynthesis. In this context, the synthesis of new porphyrin quinones with a cis-or trans-1, 4-disubstituted cyclohexylene bridge linking the electron donor and the electron acceptor is reported. To study the dependence of the PET rate of ...