Journal of Fluorine Chemistry

Trifluoromethylierungsreaktionen von CF3I, Te (CF3) 2, Sb (CF3) 3, Hg (CF3) 2, und Cd (CF3) 2· D mit furan, Thiophen, Pyrrol und p-Benzochinon [1]

D Naumann, J Kischkewitz

文献索引：Naumann, Dieter; Kischkewitz, Juergen Journal of Fluorine Chemistry, 1990 , vol. 46, # 2 p. 265 - 281

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被引用次数: 34

摘要

Abstract The trifluoromethylation reactions of Cd (CF 3) 2· glyme, Hg (CF 3) 2, Sb (CF 3) 3, CF 3 I, and Te (CF 3) 2 with furan, thiophene, pyrrol, and p-benzoquinone are compared under similar conditions. During the photochemical reactions the reactivity increases in the series Cd (CF 3) 2· glyme< Hg (CF 3) 2< Sb (CF 3) 3< CF 3 I< Te (CF 3) 2. Cd (Cf 3) 2 complexes do not react to form trifluormethylated compounds either by photóchemical or ...