The Journal of organic chemistry

Liquid ammonia as a dipolar aprotic solvent for aliphatic nucleophilic substitution reactions

P Ji, J Atherton, MI Page

文献索引：Claramunt, Rosa M.; Elguero, Jose; Garceran, Rafael Heterocycles, 1985 , vol. 23, # 11 p. 2895 - 2906

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被引用次数: 22

摘要

... Volume: Page: ... lone pair makes ammonia a good H-bond acceptor and liquid ammonia strongly solvates cations, as evidenced, for example, by 23 Na chemical ... For example, for 4-carbomethoxy phenol at I = 0.2 M (NaCl), K i = 0.63 M −1 and K d = 5.0 × 10 −2 M ...