Chemical Communications

Vanadium-substituted MCM-41 zeolites as catalysts for oxidation of alkanes with peroxides

R Neumann, AM Khenkin

文献索引：Neumann, Ronny; Khenkin, Alexander M. Chemical Communications, 1996 , # 23 p. 2643 - 2644

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被引用次数: 48

摘要

Substitution of transition metals into the framework of mol- ecular sieves has led to a burst of activity in the use of these compounds as 'stable' catalysts for the oxidation of hydrocar- bons. Most frequently, hydrogen peroxide is used as oxidant, but the use of other peroxidic compounds and also molecular oxygen has been reported. A special challenge is the oxidation of alkanes due to their extremely low reactivity. Titanium- substituted silicalite- 1, TS- 1, was found ...