Studies towards the total synthesis of taxoids: a rapid entry into bicyclo [6.4. 0] dodecane ring system. Part 1

…, JQ del Moral, JIM Hernando, P Potier, L Toupet

文献索引：Arseniyadis, Simeon; Rico Ferreira, Maria Del Rosario; Del Moral, Jose Quilez; Hernando, Jose Ignacio Martin; Potier, Pierre; Toupet, Loic Tetrahedron Asymmetry, 1998 , vol. 9, # 22 p. 4055 - 4071

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被引用次数: 11

摘要

We report a short and stereocontrolled synthesis of the taxoid BC-subunit (+)-5 embodying the whole carbon framework and most of the required oxygen functionalities for further elaboration. Enantiomeric purity was secured at an early stage by resolution involving derivatization with (S)-2-acetoxypropionyl chloride on (±)-10b.