Organic letters

Phenylene ethynylene diazonium salts as potential self-assembling molecular devices

DV Kosynkin, JM Tour

文献索引：Kosynkin, Dmitry V.; Tour, James M. Organic Letters, 2001 , vol. 3, # 7 p. 993 - 995

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被引用次数: 72

摘要

While the interface conductance is expected to drop exponentially as the distance between the conjugated π-system of the molecular electronic device and the metal surface increases, 3 the “alligator clip” most widely used to attach molecular wires to metal substrates, the thiol group, 4 unavoidably introduces an extra atom and a covalent bond into the molecule-to-metal gap. In an attempt to alleviate this problem, we utilized the well-established reactivity of ...