Synthesis of dendritic catalysts and application in asymmetric transfer hydrogenation

…, L Jiang, JG Deng, H Liu, J Zhu, YZ Jiang

文献索引：Chen, Ying-Chun; Wu, Tong-Fei; Deng, Jin-Gen; Liu, Hui; Cui, Xin; Zhu, Jin; Jiang, Yao-Zhong; Choi, Michael C. K.; Chan, Albert S. C. Journal of Organic Chemistry, 2002 , vol. 67, # 15 p. 5301 - 5306

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被引用次数: 84

摘要

Fréchet-type core-functionalized chiral diamine-based dendritic ligands and hybrid dendritic ligands condensed from polyether wedge and Newkome-type poly (ether-amide) supported multiple ligands were designed and synthesized. The solubility of hybrid dendrimers was found to be finely controlled by the polyether dendron. The catalytic efficiency and recovery use of dendritic ruthenium complexes were compared in the transfer hydrogenation of ...