Redox states of well-defined π-conjugated oligothiophenes functionalized with poly (benzyl ether) dendrons

JJ Apperloo, RAJ Janssen, PRL Malenfant…

文献索引：Apperloo, Joke J.; Janssen, Rene A.J.; Malenfant, Patrick R.L.; Groenendaal, Lambertus; Frechet, Jean M.J. Journal of the American Chemical Society, 2000 , vol. 122, # 29 p. 7042 - 7051

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被引用次数: 85

摘要

The redox states of a series of well-defined hybrid dendrimers based on oligothiophene cores and poly (benzyl ether) dendrons have been studied using cyclic voltammetry and variable-temperature UV/visible/near-IR spectroscopy. The oxidation potentials and the electronic transitions of the neutral, singly oxidized, and doubly oxidized states of these novel hybrid materials have been determined as a function of oligothiophene conjugation ...