Thermal Decomposition of tert-Butyl 1-Arylcycloalkanepercarboxylates
…, RJ Trocino, WR Rozich, IC Sabeta…
文献索引：Wolf, Richard A.; Trocino, Richard J.; Rozich, William R.; Sabeta, Isidore C.; Ordway Jr., Richard J. Journal of Organic Chemistry, 1998 , vol. 63, # 12 p. 3814 - 3820
A series of tert-butyl 1-arylcycloalkyl peresters was prepared, and the rate constants for the peresters' thermal decomposition were measured at several temperatures. The decomposition rates and aryl-substituent effects on the decomposition rates for the three series of peresters are remarkably similar to each other and to the acyclic α, α- dimethylbenzyl analogue previously investigated. The magnitude of the activation ...
