Deprotonation of tertiary amine cation radicals. A direct experimental approach

JP Dinnocenzo, TE Banach

文献索引：Dinnocenzo, J. P.; Banach, T. E. Journal of the American Chemical Society, 1989 , vol. 111, # 23 p. 8646 - 8653

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被引用次数: 141

摘要

Abstract: The tertiary amine cation radical salt p-An2NCH3'+ AsF6-was prepared by oxidation of the corresponding amine with dioxygenyl hexafluoroarsenate. The cation radical salt was characterized by EPR spectroscopy, by magnetic susceptibility, by UV-vis spectroscopy, and by single-crystal X-ray diffraction. The reaction of the salt with quinuclidine produced at 1: l ratio of pAn, NCH3 and the adduct 1. Four possible ...