Hydrolysis kinetics and mechanism of N'-(3-N-methylcarbamoyloxyphenyl)-N, N-dimethylformamidine

A Čegan, J Šlosar, M Večeřa

文献索引：Cegan, Alexandr; Slosar, Jaroslav; Vecera, Miroslav Collection of Czechoslovak Chemical Communications, 1980 , vol. 45, # 4 p. 1065 - 1071

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被引用次数: 3

摘要

Abstract Hydrolysis of N'-(3-N-methylcarbamoyloxyphenyl)-N, N-dimethylformamidine (I) has been studied in mixture water-dioxane (4: 1) at pH 1 to 13. The hydrolysis rates of methylcarbamoyl and dimethylformamidine groups are comparable within pH range 4 to 10, and they differ by as much as several orders of magnitude in pH ranges 1-3 and 11-13. The hydrolysis products of the whole pH range have been determined by paper ...