Journal of the American Chemical Society

Synthesis of 3, 5, 7-triketo acids and esters and their cyclizations to resorcinol and phloroglucinol derivatives. Models of biosynthesis of phenolic compounds

TM Harris, RL Carney

文献索引：Harris,T.M.; Carney,R.L. Journal of the American Chemical Society, 1967 , vol. 89, p. 6734 - 6741

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被引用次数: 45

摘要

Abstract: Seven 3, 5, 7-triketo acids were prepared by carboxylation of tte trianions of the coiresponding triketones. Four of the acids were obtained as crystalline solids; the remaining three were oils which were not fully characterized. Cyclization of the triketo acids in aqueous buffer, pH 5.0, afforded high yields of the corresponding