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N, N, N′, N′??Tetrabutyl??3, 6??dioxaoctan??dithioamid, Ionophor mit Selektivität für Cd2+

JK Schneider, P Hofstetter, E Pretsch…

文献索引:Schneider, Juerg K.; Hofstetter, Peter; Pretsch, Ernoe; Ammann, Daniel; Simon, Wilhelm Helvetica Chimica Acta, 1980 , vol. 63, # 1 p. 217 - 224

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被引用次数: 58

摘要

Summary The dioxa-dithioamide 3 behaves as a highly selective ionophore for Cd2+ in solvent polymeric membranes. It induces cation-permselectivity in these membranes with a transference number of 1 for Cd (NO,),-and of 2 for CdCl+ olutions. In the presence of a proton carrier, 3 may be used to selectively pump Cd2+ through membranes by coupling with a pH gradient.