Reversible control of assembly and disassembly of interlocked supermolecules

KJ Chang, YJ An, H Uh, KS Jeong

文献索引：Chang, Kyoung-Jin; An, Young-Jae; Uh, Hyounsoo; Jeong, Kyu-Sung Journal of Organic Chemistry, 2004 , vol. 69, # 20 p. 6556 - 6563

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被引用次数: 16

摘要

Two kinds of interlocked supramolecular complexes that display stimulus-responsive assembly and disassembly have been described. One is a pseudorotaxane driven by hydrogen-bonding interactions between rings 2a and 2b and rods 1a and 1b. The rods contain a binding site for the ring as well as a stimulus-responsive diazo group, both of which are conformationally constrained in parallel by connecting them to a rigid xanthene ...